연료전지_3
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작성자 관리자 댓글 5건 조회 30,219회 작성일 15-04-16 17:07본문
다음은 아폴로 우주선과 우주왕복선에 사용되었던 “아폴로 형이다”
이 전지는 전해액으로 수산화칼륨 수용액을 사용하기 있기 때문에 전해액속의 수산화이온(OH-) 이 플러스극에서 마이너스 극으로 이동하고 물은 마이너스 극에서 만들어진다,
그림에 제시된 반응식을 참고하여 이해해보도록 하자.
마이너스극
H2 + 2OH- ---à 2H2O + 2e-
(수소) (수산화이온) (물 생성)
플러스극
O2 + H2O + 2e- ---à O2 H- + O H-
(산소) (과산화수소이온)
O2 H- ------à O H- + ½O2
양변을 각각 더하면
½O2 + H2O + 2e- ---à. 2OH-
전체방정식
H2 + ½ O2 ----à. H2O
전체반응식은 제미니 형과 동일하다, 이렇게보면 우주비행사가 연료전지에서 음료수를 얻는 경우에도 산소가 든 플러스극의 물을 마시는것과 수소가 든 마이너스 극의 물을 마시는 것은 서로 차이가 있다. 아마 맛도 미묘하게 틀릴 수 있기 때문에, 식후 한잔의 물을 어느 쪽에서 받아 마실지 고민에 빠질지도 모른다.
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